Have now got to the bottom of the story, the material deposited on the car is a slurry of road surfacing resulting from slot cutting operations with diamond cutters , not resurfacing work as I first thought.  Inevitably there must be some abrasive material included which if removed by rubbing could well damage the paintwork.  I don't think that a pressure washer will remove it. 
 
Any more thoughts? 
 
Thanks, 
 
Rob
                            
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                        a big heavy foam (w/up liquid) sponged all over it, and them blow off at a VERY acute angle with an air spray. Then wash/wax as per usual. 
The foam should prevent too much abrasion.
                            
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                        Don't use washing up liquid as this is one of the worst substances that will take the shine off your paintwork if used over a period of time.
                            
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                        Washing up liquid contains quite a lot of salt (as per dishwasher salt), so putting it on cars is a bad idea. Surely proprietary car washing soap should do the trick. 
 
Chris
                            
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                        Bubbles, bubbles! 
The idea was to use the foam, which will also take off a bit of polish (to which the gunge may have stuck), and then re-polish/wax.
                            
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                        Guess we're spoiled here in New York - every auto parts shop sells Bug and Tar Remover.  Dab in on, wipe it off.  Elapsed time 30 seconds.  No fuss, no muss!
                            
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                        Only trouble is the amount there is - there isn't a panel without some on and the front resembles a coat worthy of Cruella de Ville!  As mentioned, it's not just tar, there will  be bits of diamond stone cutter blade which I think will leave a scratched surface if rubbed at all.   
 
The advice given has been helpful, I should be able to get it sorted now. 
 
Rob
                            
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