100k a Vectra will need a lot of work to the suspension, if it hasn't had it already. Particularly at the back. Shocks all round most likely as well. Listen for knocks, and check the inside edge of rear tyres for wear.
The 1.9CDTI 150hp engine is 16v, and has swirl flaps in the inlet manifold. They fail, a lot. They're almost always knackered by 80k. Check any high milers have had the inlet manifold replaced, and the EGR will need to be done as well. Later Vectras stopped using the F40 gearbox and went to the M32. The M32 is made out of chocolate, and will most likely be near end of life by 100k, especially if the oil hasn't been changed (not a service item). F40 is far better and will go on forever as it's rated to 400lb-ft, not the 320lb-ft of the M32.
The 1.9CDTI 120hp is a different engine, and is 8v. It doesn't suffer anywhere near as many issues, doesn't have the swirl flaps, and the EGR is much better. Also more gearbox friendly.
You'll get about 44mpg out of both engines, they're not very economical, but do perform really well.
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