There are two very different uses of the word lambda on motor cars.
One is the lambda sensor in the exhaust, which provides feedback to the engine management unit and tweaks the fuelling to keep the engine close to stoichometric.
The other use of lambda is the value reported by the gas tester during an MOT, which is where Tyro's question comes from.
As RichardW has said, the MOT lambda value is a calculated value, obtained from the ratios of the gases measured by the MOT station's analyser - it has very little real correlation with what the car's lambda sensor is reading.
HC is unburnt, or partially burnt hydrocarbons. In gas analysis, these hydrocarbons can come from two sources. First, the engine may be worn and passing oil into the combustion chamber, which cannot be fully burnt. Second, the engine may begin to misfire, or suffer from only partial combustion of the fuel. This unburnt fuel registers as HC on the gas analyser.
In formulae written about engine combustion, the greek letter lambda is used to signify the excess air ratio, and the higher the number, the weaker the mixture. However, if you have a cylinder which is partially or fully misfiring, the gas analyser will detect a mixture of gases which *wrongly* suggest a weakening of the mixture.
I think that in Tyro's case, the HC increase for 5 to 9 isn't massively significant in itself, but, I suspect that the pairing of HC and lambda numbers suggest a slight misfire which will probably be sorted out at the next service.
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