Not that I'm any sort of expert, but for me, the main thing I would be doing after getting a new set of 4 tyres is making sure they have been correctly fitted/balanced and the tracking is acceptable - try and find a completely flat (not cambered, or at least equally each side) empty bit of road and see if they pull one way or the other at a steady speed, under braking and acceleration.
I would also (see Leif's thread on some new tyres that didn't go very well) take it reasonably easy generally for a few weeks, and especially in wet (particularly damp) conditions - your new tyres may ride and handle considerably differently to your previous set. Sometimes you can get a bad set, ones that for some reason just don't match your car very well (not always easy to ascertain before buying them), have been poorly fitted or don't work as well as they should if the tracking was out.
I'm not sure whether the coloured lines on the tread are there to indicate when they are 'worn in' (and correctly/evenly, i.e. properly fitted and tracking ok) - hopefully others more in the know can asnwer that and more.
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