I find coolant has a very distinctive smell. Have a sniff in your expansion tank when it's cool - obviously. Do you get the same smell inside the car?
If it's the coolant, then the level will be dropping in the expansion tank, is it?
Have you done the obvious checks, like replacing the pollen filter and clearing all the detritus (dead leaves, twigs etc.) that collect in the plenum chamber for the heater?
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