The usual advice is to scan for fault codes, but as it's a PD I'll hazard a guess for you, based on the symptoms you describe.
VAG in their infinite technical wisdom potted the engine temperature transducers in hard epoxy. When heat cycled (remember where they live) the differential expansion within a rigid brass tube breaks the delicate thermistor elements and they fail intermittently open circuit.
The early transducers have a black body, the later (slightly improved) version is green. Good replacements are available cheaply from GSF. Remember to renew the "O" ring seal and buy a new plastic "horseshoe" retaining clip if you think you might lose or break the old one.
It's located at the transmission end of the of the cylinder head next to the tandem pump. Replenish any lost coolant with the correct G12 mixture and vent as required. It may take a few start cycles to extinguish the light - if this is the problem.
659.
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