If you have pressure building up in the header tank it will either be the head gasket or head that's leaking. A leaking gasket doesn't in itself cause the engine to boil just that the pressure blows most of the coolant out, then it boils. Look round the filler cap and overflow pipe for signs of dry antifreeze.
If the thermostat has stuck closed it will boil and eject the coolant but takes sometime to do that, if the radiator is geting hot then the thermostat will probably OK. The temperature that your engine reached will probably have caused the gasket to fail anyway.
Drive with your heater on, if the gasket is leaking the heater will go cold before the coolant boils.
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