Being 2002 model this should have the 1.9PD, an efficient unit & not renown for smoke.
My wife has a Passat with the same engine & would expect something to be wrong if we didn't get well into the 50's MPG on a run over 10 miles. But it will also depend on how you drive as well.
Her car has 130k miles on the clock & I removed the EGR for a clean for the 1st time recently but it wasn't unduely caked up with soot.
You really need someone with VCDS to scan live data & see what is out of kilter.
The water temperature sensor is a common failure & would cause a richer fueling if failed. They have 2 sensors in one. One output connects to the temperature guage while the other connects to the ECU which controls the fueling. So you can only look at this via a diagnostic like VCDS.
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